And ist should be (for a 4.0.x server) like this:
Select_priv
Insert_priv
Update_priv
Delete_priv
Create_priv
Drop_priv
Reload_priv
Shutdown_priv
Process_priv
File_priv
Grant_priv
References_priv
Index_priv
Alter_priv
Show_db_priv
Super_priv
Create_tmp_table_priv
Lock_tables_priv
Execute_priv
Repl_slave_priv
Repl_client_priv
ssl_type
ssl_cipher
x509_issuer
x509_subject
max_questions
max_updates
max_connections
As I wrote in your ticket you should run the fix-privileges script.
Looks like this server has been (incorrectly) upgraded form 3.23.x